Main, Sasuke, Iruka, Neji - for controlling their move 1 if you don't have enough refines to beat them.
High float into low float to proc genjutsu before paralyze and acupuncture.

Main, Anko, Iruka, Jiraya - for massive damage, no control.

Main, Tobi, Sasuke, Hinata, for all around good stuff but depends on having highest initiative move 1.