For main you can either go fire main, since mirror is always good. Else water main , since you can take advantage of madara barrier and poison teams to death.As for the 4th ninja ,Hokage tsunade is smthin i will use if and only i can get her . Or u can try hanzo ( for madara chase if not have KOH ), kurenai (Extra mirror) and maybe another healer.
Not to forget Earth main oso can be quite good since he can give Defense knowledge passive which wont be cleared by madara, or the one which increases the combo rate of all male units .
Have a good day :D
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